Metal Vinylidenes and Allenylidenes in Catalysis From Reactivity to Applications in Synthesis Book
Catalytic transformations of alkynes have recently led to tremendous developments of synthetic methods with useful applications in the synthesis of natural products and molecular materials. Among them, the selective activations of terminal alkynes and propargylic alcohols via vinylidene- and allenylidene-metal intermediates play an important role, and have opened new catalytic routes toward anti-Markovnikov additions to terminal alkynes, carbocyclizations or propargylations, in parallel to the production of new types of molecular catalysts. METAL VINYLIDENES AND ALLENYLIDENES IN CATALYSIS FROM REACTIVITY TO APPLICATIONS IN SYNTHESIS.
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